Hi Tony,
In my response I didn't mean to imply that for larger scale projects use cases are the best way to model the "AS-IS" of an organization.
If I was forced to pick only one tool I would choose a process flow diagram, probably using BPMN (Business Process Modeling Notation) to model it. Nothing better to model business processes than a business process diagram.
If I was allowed to use two tools then I would definitely add the Business Entity Model because before even talking about how data flows within a system I would want to define the actual data to ensure that everybody knows what we are talking about.
Then I would create data flow diagrams which shows how data (as defined by the Business Entity Model) flows among processes. I agree with you that an ERD would not be needed at this point - thanks for correct me on this one.
- Adrian